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Home » Archives for November 2024

November 2024

Archives for November 2024

E.S. Freed and Charles O. Hill are pictured in a laboratory in Science Hall. The photo is in black and white and was taken between 1913 and 1915.

UT Alum Left Lasting Impact on Chemical Extraction

November 21, 2024 by Jennifer Brown

E.S. Freed and Charles O. Hill are pictured in a laboratory in Science Hall. The photo is in black and white and was taken between 1913 and 1915.

Chemistry is frequently called the central science. Because it uncovers knowledge critical to the understanding of matter, it is important to a number of disciplines. Discoveries and innovation in chemistry can have far-reaching implications that last for decades. The great-grandson of alumnus Edgar Stanley Freed came face to face with this phenomenon when he began researching his family’s history.

E. Stanley Freed came to the University of Tennessee, Knoxville, in 1909. He joined the Department of Chemistry, earning a bachelor’s degree in chemical engineering in 1913. Freed then served two years as an assistant professor at UT, until beginning graduate studies at the Massachusetts Institute of Technology (MIT).

Freed received one of only four PhD degrees MIT awarded in 1918. In 1920, he began working in the New York laboratory of the Chile Exploration Company, and in 1922 he relocated to Chile.

Building a Legacy

By the time Freed arrived in Chile, the nitrate industry had been suffering for a number of years, due to the development of synthetic nitrate. The Chile Exploration Company sent Freed to an experimental plant for nitrate extraction working with caliche, a type of soil containing a variety of mineral deposits including nitrate salts. He was tasked with modernizing the industry by developing better, more efficient processes.

Upon his arrival, Freed realized little research had been done on the caliche itself and its chemical properties. He quickly began developing a body of knowledge that could be used to inform extraction methods. Over the course of his career, Freed and a number of additional researchers made advancements in mineral extraction from caliche.

By the mid-1940s, Freed had begun to pursue not only nitrates, but possibly useful byproducts. He would eventually be credited with developing the solar evaporation pond, a method that uses the natural process of evaporation in a series of open-air ponds to extract a variety of products.

Freed’s evaporation ponds became an industry staple and are still used today. This method has been used to efficiently recover nitrates, iodine, potassium, and even lithium. It is still considered a key element of production in industry, and contributes to a range of fields including pharmaceuticals, construction, and agriculture. Lithium alone has been used to power personal electronics, medical devices such as pacemakers, and electric vehicles. Freed’s development helped prop up a declining industry and simplified access to materials that have been used to create a number of elements of modern life.  

Preserving History

Book cover: Edgar Stanley Freed, Los Guggenheim y La Industria Del Salitre

Sebastian Freed-Huici began investigating his great-grandfather’s history in earnest at the age of 14. Freed-Huici had been taught that the nitrate industry in Chile collapsed due to a combination of the Great Depression and the creation of synthetic nitrate. However, he knew that Freed had been working in the industry up until his death in 1950. Unable to reconcile these differing timelines, Freed-Huici began digging into his family’s records, uncovering more of Freed’s story.

“My grandmother kept a folder about my great-grandfather with some newspaper clippings and other information about him,” said Freed-Huici. “She also had his diplomas from the University of Tennessee and MIT. After that, I looked for information about him online and then started calling historians.”

Freed-Huici eventually connected with a historian at the Archivo Nacional de Chile who had recently uncovered boxes of documents about and belonging to the late E. Stanley Freed. It was in communicating with the historian, Pablo Muñoz, that Freed-Huici learned of his great-grandfather’s achievements.

Galvanized by this discovery, Freed-Huici set out to share Freed’s story and, in the last few years, all that effort has begun to see results. In 2021, a book detailing Freed’s life and work was published. Edgar Stanley Freed, Los Guggenheim y la Industria del Salitre was written by Patricio A. Espejo Leupin and included images and documents provided by Freed-Huici. A second book, written by industry professional Beatriz Oelckers and titled El Hombre Que Más Sabía del Caliche en el Mundo, was published in August 2024.

Freed-Huici, now a PhD student in economics at the University of Chicago, said he was inspired by his great-grandfather and wanted to share his story.

“I realized that this is not a story of the past. It’s a story of the present, because all these systems are used today,” said Freed-Huici. “His legacy is alive, and I want people to know about it. For the 28 years he was in Chile, he never stopped working on this problem. He never stopped researching and experimenting and looking for answers, and I find that very inspiring.”

Filed Under: News Tagged With: alumni

UT researchers Yanhong Gu and Kevin Smith work at the National High Magnetic Field Laboratory.

UT Team Finds Unexpected Behavior in Magnetized Material

November 18, 2024 by Logan Judy

Filed Under: Featured, Musfeldt, News

Selected Faculty Updates and Publications for 2024

November 4, 2024 by Jennifer Brown

Michael Best, professor and associate head of undergraduate education, recently published “Nuclear phosphoinositide signaling promotes YAP/TAZ-TEAD transcriptional activity in breast cancer” in The EMBO Journal. Best and then-postdoctoral researcher Jinchao Lou worked with a team including researchers from the Eppley Institute for Research in Cancer and Allied Diseases and the Fred and Pamela Buffett Cancer Center. Both institutions are part of the University of Nebraska Medical Center.

Assistant Professor Joshua Baccile’s publication “Biological Demands and Toxicity of Isoprenoid Precursors in Bacillus Subtilis Through Cell-Permeant Analogs of Isopentenyl Pyrophosphate and Dimethylallyl Pyrophosphate” was featured on the cover of ChemBioChem. Graduate students Zack Hulsey and Dillon McBee, and undergraduate student Makayla Hedges were co-authors of this publication.

Professor Shawn Campagna’s research group has had a busy year. Seven members have delivered 11 talks or poster presentations at conferences and events, including both the spring and fall meetings of the American Chemical Society, the 3rd Annual Biomembranes Symposium, and the American Society for Mass Spectrometry national meeting.

Assistant Professor Yingwen Cheng was recently awarded a grant by the Department of Energy for a project entitled High Energy and Cycling Stable All-Weather Aqueous Zn Batteries. Cheng plans to develop alkaline-manganese dioxide batteries using minerals with robust supply chains as an alternative to lithium-ion batteries. He has also been named a StART awardee, a program managed by the UT-Oak Ridge Innovation Institute to support collaborations between UT and ORNL researchers.

Associate Professor Ampofo Darko’s group recently published “Chromogenic Detection of the Organophosphorus Nerve Agent Simulant DCP Mediated by Rhodium(II,II) Paddlewheel Complexes” in ACS Sensors. Graduate students Eric Fussell, Ernest Bennin, and Sarah Hirschbeck were co-authors on the publication. At the department’s 2024 Honor’s Day, Darko group member Bukola Ogunyemi was given an Outstanding PhD Candidate Award.

Assistant Professor Thanh Do’s group published “The Rise and Fall of Adenine Clusters in the Gas Phase: A Glimpse into Crystal Growth and Nucleation” in Analytical and Bioanalytical Chemistry. The article was featured on the publication’s cover and included graduate students Damilola Oluwatoba and Happy Safoah as co-authors.

Assistant Professor Fred Heberle recently published “Neutron spin echo shows pHLIP is capable of retarding membrane thickness fluctuations” in Biomchimica et Biophysica Acta (BBA) Biomembranes. The team on this project included researchers from the UT departments of chemistry, physics and astronomy, and biochemical, cellular, and molecular biology. This multidisciplinary group also included ORNL researchers working in the Labs and Soft Matter Group of the Neutron Scattering Division, the Computational Science and Engineering Division, and the Center for Nanophase Materials Sciences.

The research group of Professor David Jenkins has had an exciting year. Three graduate students successfully defended their dissertations in one semester. Two students published first-author papers, and several group members presented at conferences, including the National Meeting of the American Chemical Society and the 51st Annual National Organization for the Professional Advancement of Black Chemists and Chemical Engineers Meeting. Jenkins’ previous publication in ACS Applied Materials and Interfaces was featured in Advances in Engineering.

In just one semester at UT, Assistant Professor Ziying (Nancy) Lei has hit the ground running. Lei has been collecting samples and training graduate students on measuring urban air quality across UT campus, and was recently granted a research permit ahead of a developing collaboration with the National Park Service Research Team at the Great Smoky Mountains National Park. She will also be teaching a new Environmental Chemistry class in spring 2025.

Professor Janice Musfeldt’s work “Structural phase purification of bulk Hfo2:Y through pressure cycling” was published in The Proceedings of the National Academy of Sciences, one of the world’s most cited and comprehensive multidisciplinary journals. She also began a new lecture series featuring women researchers, the first of which was held on the 2024 UN International Day of Women and Girls in Science and featured Karin Rabe, Board of Governors Professor of Physics at Rutgers University.

Associate Professor Sharani Roy published “Semiempirical molecular-orbital calculations of dissociation energies of small molecules containing light elements” in Molecular Physics. At this year’s Honor’s Day event, graduate student Dakota Landrie, a member of Roy’s group, was awarded the inaugural Dr. Robert A. and Phyllis F.J. Yokley Endowed Fellowship.

Konstantinos Vogiatzis, associate professor of theoretical and computational chemistry, received the Pariser Faculty Poster Award at the American Conference on Theoretical Chemistry. The award was in recognition of his poster presentation “Exploration of the Two-Electron Correlation Space with Data-Driven Quantum Chemistry.”

Professor Bin Zhao recently published “Effect of Grafting Density on the Crystallization Behavior of Molecular Bottlebrushes” in Macromolecules. This paper continues Zhao’s work with bottlebrush polymers and was co-authored by former graduate students Ethan Kent and Michael Kelly.

Filed Under: Uncategorized

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